Secret Garden comes to mind, the FL is quite cold towards the ML and irritated by him. (well both sometimes irritated by each other lol)
Another I watched recently is Full House, more of a cat/dog interaction though. I think the most fun scenarios I find is where the ML and FL have a cat and dog kinda relationship, I think that makes for funnier scenes and dialogue.
Another series is My love from the stars (aka. You who came from the stars), the FL is very obnoxious in the beginning towards the ML who is kinda just charming in his own cold way.
But I admit I'm having difficulty coming up with series where this is the specificially the case, usually this is flipped, the ML is cold towards FL.
And as you mentioned, usually this is only in the beginning where the FL rejects the advancements of the ML, but eventually falls for him. I think pretty much every kdrama romance is like that :)