I second Empress Ki and Scarlet Heart for the ML with the dark side, plus:
The Last Empress - one of the MLs is full on dark and once he falls for the FL is very jealous
When a Man's in Love - the ML was thug at first, definitely possessive and has a dark side. The second ML wouldn't leave the FL alone too.
Born Again - the ML is extremely dark, he has a sweet side too. The rivalry between him and the 2nd ML gets really intense.
Missing You - it's the second ML who is dark here. The fight for the FL gets really heated and dark.
Discovery of Romance - no dark ML, but the love triangle has a heavy presence.
Failing In Love - one of the MLs is dark and jealous
For other intense love triangles with jealousy try
When I Was the Most Beautiful - airing now
And
To all the Guys Who Loved Me - recently completed its run